In October 1719, the Yearly Meeting of the Society of Friends for Philadelphia and the Jersies reached consensus on a "book of discipline" governing the "establishment and order of meetings." The regulations covered both the conduct of the Quarterly and Monthly Meetings and the personal comportment of individual members, refining the bureaucratic structure of the meetings and laying out the powers of Overseers and other officials. It touches upon marriage (mandating endogamy), burial, and attendance at meetings, and cautions Friends to plainness of speech and dress, drinking, smoking, backbiting, and gaming. This version of the Book of Discipline is a manuscript copy made for the American Philosophical Society in 1820 "from and antient Copy in the possession of Timothy Matlack, Esqr."

Personal and professional correspondence of the chemist Robert Hare, including drafts of letters to editors of journals on such varied topics as fish guano, slaughterhouses, paper money, and the meaning of the term "Yankee annexations." The collection originally contained over 300 scrolls, since disbound, which contained drafts of letters, essays, and lectures, composed by Hare on ordinary sheets of paper, then pasted end to end, and rolled up. The essay and lecture topics include: chemistry, storms, slavery, currency, fire-fighting, capital punishment, railroads, the Smithsonian Institution, Michael Faraday, religion and Spiritualism, riots in Philadelphia, epidemics, underwater blasting, and Ralph W. Emerson; there is some verse. The collection also contains an account book of Hare and his wife, 1806-1829 (180 pp.; B/H22#3); a volume by Hare on Cyclones (tornadoes), n.d. (ca. 60 pp.; B/H22#4); and Samuel Powel, Jr.'s "Short notes on a course of antiquities at Rome... under M. Byre Antiquarian," 1764. (60 pp.).